Basic pH Tutorial
What is pH
pH is the Unit of Measure used to express the degree of acidity of a substance.
The centimeter is a unit measure of length. The gram is a unit measure of weight. So, pH is the unit measure we use to say how much acid is in a substance. The pH scale goes from 0 to 14. A pH of 0 means a very high acid activity. Substances such as lemon juice and vinegar are acidic with pH values of 2 to 3. Nitric acid and hydrochloric acid are very strong with pH values of 0, while stomach acid has a pH of 1. Addition of a strong acid, such as sulfuric acid ( H2SO4 ) to water makes the resulting solution very high in active acid concentration. This is called an acidic solution.
On the other end of the scale are the alkaline substances, which range from 8 to 14. Common alkalis are seawater (pH 8), household ammonia (pH 11), oven cleaners (pH 13), and the very strong alkali, sodium hydroxide (pH 14). The addition of a strong base or alkali material, such as sodium hydroxide ( NaOH ), to water makes the resulting solution very low in active acid concentration. This is called a very basic or alkali solution.
In between these two extremes is a pH of 7. This is the pH of pure water. Water, which is neither very acidic nor very alkali, is said to be neutral.
Technically, the scale actually refers to the concentration of positively-charged hydrogen (H+) ions and negatively-charged hydroxyl (OH-) ions in solution. More hydrogen ions than hydroxyl ions makes an acidic solution, while an alkaline solution contains more hydroxyl ions than hydrogen ions. The pH scale is a logarithmic one, meaning that each pH unit has 10 times as many hydrogen ions as the unit above it. So, at pH 4, there are 10 times more hydrogen ions than at pH 5 and 100 times more hydrogen ions than at pH 6.
The following table will give you an idea of the pH values of common substances:
|
Substance |
pH Value |
|
Stomach acid |
1.0 |
|
Lemon Juice |
2.4 |
|
Vinegar |
2.8 |
|
Orange Juice |
3.0 |
|
Tomato Juice |
4.0 |
|
Black Coffee |
5.0 |
|
Detergent |
6.5 |
|
Milk |
6.8 |
|
Blood |
7.2 |
|
Seawater |
8.0 |
|
Baking soda |
9.0 |
|
Milk of Magnesia |
10.7 |
|
Domestic Bleach |
11.0 |
|
Caustic Soda |
14.0 |
(From General Chemistry by Brady and Humiston, 1986).
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Why
pH is Important
The pH or acidity of a solution is important in many different areas:
In Biochemistry ...
The pH of our blood is normally controlled to within a few tenths of a pH
unit by our body chemistry. If our blood pH changes as much as half a pH
unit, serious illness will result. Proper skin pH is essential for a
healthy complexion. The pH of one's stomach directly affects the digestive
process.
In Agronomy ...
The pH of the soil regulates the availability of nutrients for plant
growth, as well as the activity of soil bacteria. In alkaline soils ( pH 8
and above ) the amount of nitrogen, phosphorus, iron and other nutrients
in solution become so low that special treatment is necessary to insure
proper growth.
In Food Science ...
The efficient production of food products depends upon careful pH control.
The proper curd size, uniformity, and structure of cottage cheese are
directly related to the pH at cutting time. Yeast can ferment and leaven
dough only within certain pH limits. Jelly will not gel properly unless
the pH is in the 3.5 region.
In Chemical Research
and Engineering ...
Accurate pH measurement is necessary to the study of many chemical
processes. The researcher needs to know the pH at which a chemical
reaction proceeds at its fastest in order. to understand the reaction. The
engineer uses the information to develop practical commercial processes.
In Environmental Research
and Pollution Control ...
The pH of a river or lake is important in maintaining a proper ecological
balance. The pH of the water directly affects the physiological functions
and nutrient utilization by plant and animal life. Extremes in pH can
reduce lake to a lifeless, smelly bog.
Protecting our waterways requires constant monitoring of industrial effluent. Plating and metal finishing plants tend to produce acidic waste water, as do mining operations, Chemical plants often have very alkaline waste water. pH measurements are used as a guide to the proper neutralization of these plant wastes, as well as to monitor the final effluent quality. Occasionally, an acidic stream can be combined with an alkaline stream to produce a final stream which is close to neutral. pH measurements assure the proper management of this cost saving technique.
From pH Simplified by Robert J. Joyce, Markson Science Inc.
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